Cooling for Chemical Industry

Applications by Sector

Cooling for Chemical Industry

Chillers and temperature controllers for chemical processes and classified areas

Cooling and thermal control systems for chemical industry. Temperature from -20°C to +150°C with ±0.5°C precision. Equipment for classified areas (Ex d/Ex e), 316L stainless steel corrosion-resistant materials. Solutions for exothermic reactions, distillation, crystallization and critical processes.

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Technical Specifications

-20°C a +150°C
Temperature
±0,5°C
Precision
10 a 2.000 kW
Capacity
Water/Glycol/Oil
Fluid
Ex d/Ex e
Classification
Inox 316L
Material

Process Requirements

Exothermic Reactors
Temperature:Variable per reaction
Precision:±0,5°C

Heat removal in polymerization, oxidation, neutralization and sulfonation reactions. Heat removal rate controls reaction rate and process safety.

Endothermic Reactors
Temperature:Per process
Precision:±1°C

Heat supply for energy-absorbing reactions such as cracking and dehydrogenation.

Distillation and Rectification
Temperature:Per boiling point
Precision:±1°C

Condensers and reboilers for distillation columns. Precise control is essential for efficient component separation.

Crystallization
Temperature:-10°C a +60°C
Precision:±0,5°C

Cooling ramp control for uniform crystal formation. Cooling rate determines crystal size and purity.

Polymerization
Temperature:Per polymer
Precision:±0,5°C

Critical thermal control for molecular weight, distribution and polymer properties. Highly exothermic reactions require high cooling capacity.

Chemical Storage
Temperature:15°C a 25°C

Climate control of tanks and raw material warehouses to maintain stability and safety.

Control Room
Temperature:22°C a 24°C
Humidity:40% a 60% UR

Climate-controlled environment for electronic equipment, SCADA systems and operators.

Quality Control Laboratory
Temperature:20°C a 25°C
Humidity:45% a 55% UR
Precision:±1°C

Controlled environment for physicochemical analyses and analytical instrumentation.

Technical Analysis

Thermal Engineering for Chemical Processes

The chemical industry presents some of the most complex challenges in industrial thermal control. Chemical reactions are often accompanied by the release or absorption of heat, and precise temperature control is critical for safety, product quality, and process efficiency.

Process Types and Thermal Requirements

Each type of chemical process has specific thermal control requirements:

Process Thermal Characteristic Control Requirement
Polymerization Highly Exothermic Rapid heat removal, ±0.5°C
Neutralization Exothermic Maximum temperature control
Crystallization Controlled cooling Precise cooling ramp
Distillation Heating and Condensation Stable condenser temperature
Fermentation Moderately Exothermic Narrow temperature range

Safety in Chemical Processes

Safety is an absolute priority in the chemical industry. Refrigeration systems for this industry must consider:

  • Hazardous Locations: Ex d (explosion-proof) or Ex e (increased safety) certified equipment for areas with explosive atmospheres
  • Runaway Reactions: Emergency cooling capacity to control uncontrolled reactions
  • Compatible Materials: Selection of materials resistant to process chemicals
  • Redundancy: Backup systems to ensure continuity of thermal control
  • Interlocks: Integration with plant Safety Instrumented Systems (SIS)

Heat Transfer Fluids

The choice of heat transfer fluid depends on the temperature range and the process:

  • Water: 5°C to 90°C - Higher efficiency, lower cost, ideal for most applications
  • Water/Glycol: -20°C to 90°C - For temperatures below 5°C, with antifreeze protection
  • Thermal Oil: -20°C to 350°C - For temperatures above 90°C or processes requiring heating and cooling
  • Brine: -40°C to 0°C - For moderate cryogenic applications

System Sizing

Correct sizing considers multiple factors:

  • Heat of reaction (kJ/mol or kW)
  • Reaction rate and cycle time
  • Heat exchange area available in the reactor
  • Overall heat transfer coefficient (U)
  • Log Mean Temperature Difference (LMTD)
  • Safety margin for peak demand

Helioterm conducts detailed process studies for precise sizing, ensuring adequate capacity without oversizing.

Sector Challenges

Exothermic Reactions

Temperature control in chemical reactions that release intense heat. Cooling capacity must be sufficient to maintain temperature even at peak conditions, preventing runaway reactions.

Distillation Processes

Maintaining precise temperatures in distillation column condensers. Variations affect separation efficiency and product purity.

Controlled Crystallization

Thermal control for crystallization and precipitation processes. Cooling rate determines the size, shape and purity of formed crystals.

Batch and Continuous Reactors

Reactor cooling with high precision for product quality control. Batch reactors require fast response; continuous reactors require stability.

Classified Areas (Ex)

Equipment must be certified for operation in potentially explosive atmospheres, meeting ATEX/IECEx standards.

Corrosion Resistance

Aggressive chemical environments require special materials such as 316L stainless steel, Hastelloy or special coatings.

Safety System Integration

Cooling systems must integrate with SIS (Safety Instrumented Systems) and respond to emergency commands.

Thermal Load Variation

Batch processes generate significant thermal load variations throughout the cycle, requiring responsive systems.

Our Solutions

Industrial Chillers

Reactor and process cooling with high thermal capacity. N+1 redundancy configurations for continuous operation.

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Temperature Controllers

Precise temperature control in reactors and tanks with heating and cooling. Range from -20°C to +150°C.

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Termochillers

Combined heating and cooling for processes requiring temperature variation during the cycle.

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Screw Compressor Chillers

High capacity for large chemical plants with continuous operation and low vibration.

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Self-Contained

Climate control for control rooms, laboratories and administrative areas with humidity control.

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Regulations and Standards

NR-20: Segurança com Inflamáveis e Combustíveis
NR-10: Segurança em Instalações Elétricas
NR-13: Caldeiras, Vasos de Pressão e Tubulações
ABNT NBR IEC 60079: Atmosferas Explosivas
API 2510: Design de Instalações de GLP
NFPA 30: Código de Líquidos Inflamáveis e Combustíveis
ISO 14001: Sistema de Gestão Ambiental
OSHA PSM: Process Safety Management
IEC 61511: Sistemas Instrumentados de Segurança

Benefits for Your Business

±0.5°C precision in critical processes for product quality
Equipment certified for classified areas (ATEX/IECEx)
Corrosion-resistant materials (316L stainless steel, Hastelloy)
N+1 redundancy for continuous and safe operation
Real-time remote monitoring via SCADA
Compliance with NR-10, NR-13 and NR-20 standards
Integration with safety instrumented systems (SIS)
Wide temperature range (-20°C to +150°C)
Specialized technical support for chemical processes
Complete documentation for audits and certifications

Success Case

Specialty Polymers Plant - Bahia

Design and implementation of cooling system for 4 polymerization reactors of 20 m³ each. The solution included 2 chillers of 300 TR with redundancy, chilled water system at 5°C, individual temperature controllers for each reactor and integration with plant safety system.

Temperature control ±0.3°C throughout the entire reaction cycle
Zero runaway reaction incidents in 5 years of operation
15% increase in productivity with optimized cycles
22% reduction in energy consumption vs. previous system
Consistent polymer quality (PDI < 1.5)
Full compliance with NR-20 and ISO 14001 certification
Seamless integration with existing SCADA system
ROI achieved in 20 months

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